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|Title:||Metallosupramolecular chemistry of AgI complexes with azobis(2-pyridine) and its derivatives|
|Citation:||Australian Journal of Chemistry, 2016; 69(6):612-617|
|Siji Rajan, F. Richard Keene and Peter J. Steel|
|Abstract:||Reactions of three azobis(2-pyridines) with silver salts lead to 1D coordination polymers whose structures have been determined by single crystal X-ray crystallography. The azobis(2-pyridines) consistently act as di-bidentate ligands that bridge silver atoms separated by distances ranging from 5.49 to 5.82A ° . Two of the coordination polymers consist of chains in which consecutive bridging ligands are orthogonally oriented. The other polymer has a considerably more complicated structure due to the more intimate involvement of the trifluoroacetate counteranions, which also act as bridges between silver centres.|
|Rights:||Journal compilation © CSIRO 2016|
|Appears in Collections:||Chemistry publications|
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