Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/112662
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Type: Journal article
Title: Metallosupramolecular chemistry of AgI complexes with azobis(2-pyridine) and its derivatives
Author: Rajan, S.
Keene, F.
Steel, P.
Citation: Australian Journal of Chemistry, 2016; 69(6):612-617
Publisher: CSIRO Publishing
Issue Date: 2016
ISSN: 0004-9425
1445-0038
Statement of
Responsibility: 
Siji Rajan, F. Richard Keene and Peter J. Steel
Abstract: Reactions of three azobis(2-pyridines) with silver salts lead to 1D coordination polymers whose structures have been determined by single crystal X-ray crystallography. The azobis(2-pyridines) consistently act as di-bidentate ligands that bridge silver atoms separated by distances ranging from 5.49 to 5.82A ° . Two of the coordination polymers consist of chains in which consecutive bridging ligands are orthogonally oriented. The other polymer has a considerably more complicated structure due to the more intimate involvement of the trifluoroacetate counteranions, which also act as bridges between silver centres.
Rights: Journal compilation © CSIRO 2016
RMID: 0030049801
DOI: 10.1071/CH15560
Appears in Collections:Chemistry publications

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