Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/114139
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dc.contributor.authorKhodabandeh, A.en
dc.contributor.authorArrua, R.en
dc.contributor.authorCoad, B.en
dc.contributor.authorRodemann, T.en
dc.contributor.authorOhigashi, T.en
dc.contributor.authorKosugi, N.en
dc.contributor.authorThickett, S.en
dc.contributor.authorHilder, E.en
dc.date.issued2018en
dc.identifier.citationPolymer Chemistry, 2018; 9(2):213-220en
dc.identifier.issn1759-9954en
dc.identifier.issn1759-9962en
dc.identifier.urihttp://hdl.handle.net/2440/114139-
dc.description.abstractA series of polymerized high internal phase emulsion (polyHIPE) materials have been prepared by using a water in oil emulsion stabilized by a macro-RAFT agent, 2-(butylthiocarbonothioylthio)-2-poly(styrene)-b-poly(acrylic acid), acting as a polymeric surfactant. The pore structures of the formed polyHIPEs were closed. By removing the RAFT-endgroup of the amphiphilic macro-RAFT agent, the obtained polyHIPEs possessed an open structure with voids. The effect of the RAFT-endgroup of the amphiphilic macro-RAFT agent on the surface chemistry of the polyHIPEs is discussed. The obtained polyHIPEs via this surfactant-assisted functionalization strategies were characterized by FTIR spectroscopy, FTIR mapping, SEM, SEM-EDX, TEM, XPS as well as synchrotron-based scanning transmission X-ray microscopy (STXM). The latter technique revealed the surface chemistry of the obtained polyHIPEs and macro-RAFT agent multicomponents with a surface spatial resolution of the order of 30–100 nm.en
dc.description.statementofresponsibilityA. Khodabandeh, R. D. Arrua, B. R. Coad, T. Rodemann, T. Ohigashi, N. Kosugi, S. C. Thickett and E. F. Hilderen
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.rightsThis journal is © The Royal Society of Chemistry 2018en
dc.titleMorphology control in polymerized high internal phase emulsion templated via macro-RAFT agent composition: visualizing surface chemistryen
dc.typeJournal articleen
dc.identifier.rmid0030079207en
dc.identifier.doi10.1039/c7py01770gen
dc.relation.granthttp://purl.org/au-research/grants/arc/DP130101471en
dc.relation.granthttp://purl.org/au-research/grants/arc/FT0990521en
dc.identifier.pubid390101-
pubs.library.collectionAgriculture, Food and Wine publicationsen
pubs.library.teamDS10en
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
Appears in Collections:Agriculture, Food and Wine publications

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