Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/114174
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zheng, Y. | - |
dc.contributor.author | Jiao, Y. | - |
dc.contributor.author | Qiao, S. | - |
dc.contributor.author | Vasileff, A. | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Angewandte Chemie International Edition, 2018; 57(26):7568-7579 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.issn | 1521-3773 | - |
dc.identifier.uri | http://hdl.handle.net/2440/114174 | - |
dc.description.abstract | The hydrogen evolution reaction (HER) is a fundamental process in electrocatalysis and plays an important role in energy conversion for the development of hydrogen-based energy sources. However, the considerably slow rate of the HER in alkaline conditions has hindered advances in water splitting techniques for high-purity hydrogen production. Differing from well documented acidic HER, the mechanistic aspects of alkaline HER are yet to be settled. Herein, we present a critical appraisal of alkaline HER electrocatalysis, with a special emphasis on the connection between fundamental surface electrochemistry on single crystal models and the derived molecular design principle for real-world electrocatalysts. By presenting some typical examples across theoretical calculations, surface characterization, and electrochemical experiments, we try to address some key ongoing debates to deliver a better understanding of alkaline HER at the atomic level. | - |
dc.description.statementofresponsibility | Yao Zheng, Yan Jiao, Anthony Vasileff, Shi‐Zhang Qiao | - |
dc.language.iso | en | - |
dc.publisher | Wiley | - |
dc.rights | © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.source.uri | http://dx.doi.org/10.1002/anie.201710556 | - |
dc.subject | Alkaline hydrogen-evolution reaction | - |
dc.subject | Density-functional theory | - |
dc.subject | Hydrogen adsorption/absorption | - |
dc.subject | electrocatalysis | - |
dc.subject | mechanistic studies | - |
dc.title | The hydrogen evolution reaction in alkaline solution: from theory, single crystal models, to practical electrocatalysts | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1002/anie.201710556 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP160104866 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP170104464 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/LP160100927 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DE160101163 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FL170100154 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Zheng, Y. [0000-0002-2411-8041] | - |
dc.identifier.orcid | Jiao, Y. [0000-0003-1329-4290] | - |
dc.identifier.orcid | Qiao, S. [0000-0002-1220-1761] [0000-0002-4568-8422] | - |
dc.identifier.orcid | Vasileff, A. [0000-0003-1945-7740] | - |
Appears in Collections: | Aurora harvest 8 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.