Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/114518
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dc.contributor.authorZhang, H.en
dc.contributor.authorTian, W.en
dc.contributor.authorLi, Y.en
dc.contributor.authorSun, H.en
dc.contributor.authorTadé, M.en
dc.contributor.authorWang, S.en
dc.date.issued2018en
dc.identifier.citationJournal of Materials Chemistry A, 2018; 6(15):6265-6272en
dc.identifier.issn2050-7488en
dc.identifier.issn2050-7496en
dc.identifier.urihttp://hdl.handle.net/2440/114518-
dc.descriptionPublished on 27 February 2018en
dc.description.abstractHerein, a facile interface-induced synthesis method is first established to newly fabricate two-dimensional (2D) bilayer nanosheets of WO₃@CoWO₄ as highly efficient catalysts for enhanced photo, electro and photoelectro-chemical oxygen evolution reactions (OERs). The heterostructure and the interfacial oxygen vacancy of WO₃@CoWO₄ reduce the energy barriers in the OER. Density functional theory (DFT) calculations and material characterizations reveal that the WO₃@CoWO₄ p–n heterojunction endows the composite with a narrowed band gap for better visible-light harvesting, rapid charge transfer across the interface and a lower recombination rate of the photo-excited carriers. The interface O-vacancy vests the active Co site with an enhanced density of state (DOS) at the valence band maximum (VBM), which can increase the concentration of the photogenerated holes to improve photocatalytic and photoelectrochemical (PEC) activity. This study presents a proof-of-concept design towards low cost and multi-metal 2D/2D nanosheets for water oxidation applications.en
dc.description.statementofresponsibilityHuayang Zhang, Wenjie Tian, Yunguo Li, Hongqi Sun, Moses O. Tadé and Shaobin Wangen
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.rightsOpen Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. This journal is © The Royal Society of Chemistry 2018en
dc.titleHeterostructured WO₃@CoWO₄ bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of wateren
dc.title.alternativeHeterostructured WO(3)@CoWO(4) bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of wateren
dc.typeJournal articleen
dc.identifier.rmid0030096522en
dc.identifier.doi10.1039/c8ta00555aen
dc.relation.granthttp://purl.org/au-research/grants/arc/DP130101319en
dc.relation.granthttp://purl.org/au-research/grants/arc/DP150103026en
dc.identifier.pubid435454-
pubs.library.collectionChemical Engineering publicationsen
pubs.library.teamDS03en
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
dc.identifier.orcidWang, S. [0000-0002-1751-9162]en
Appears in Collections:Chemical Engineering publications

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