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|Title:||Biomimetic synthesis of hyperjapones F-I|
|Citation:||Australian Journal of Chemistry, 2018; 71(9):649-654|
|Hiu C. Lam, Quang D. Phan, Christopher J. Sumby, and Jonathan H. George|
|Abstract:||Hyperjapones F–I are tetracyclic meroterpenoids recently isolated from Hypericum japonicum. All four of these natural products have been synthesised using oxidative, intermolecular hetero-Diels–Alder reactions to couple their common biosynthetic precursor, norflavesone, to the appropriate monoterpene building blocks: sabinene, β-pinene, and α-pinene. The synthesis of enantiomerically pure hyperjapones H and I and comparison of their optical rotations to those of the natural samples indicated that these meroterpenoids are probably biosynthesised as either racemic or scalemic mixtures.|
|Description:||Published online: 6 July 2018|
|Rights:||Journal compilation © CSIRO 2018|
|Appears in Collections:||Chemistry publications|
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