Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/115905
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DC Field | Value | Language |
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dc.contributor.author | Lam, H. | - |
dc.contributor.author | Phan, Q. | - |
dc.contributor.author | Sumby, C. | - |
dc.contributor.author | George, J. | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Australian Journal of Chemistry: an international journal for chemical science, 2018; 71(9):649-654 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.issn | 1445-0038 | - |
dc.identifier.uri | http://hdl.handle.net/2440/115905 | - |
dc.description | Published online: 6 July 2018 | - |
dc.description.abstract | Hyperjapones F–I are tetracyclic meroterpenoids recently isolated from Hypericum japonicum. All four of these natural products have been synthesised using oxidative, intermolecular hetero-Diels–Alder reactions to couple their common biosynthetic precursor, norflavesone, to the appropriate monoterpene building blocks: sabinene, β-pinene, and α-pinene. The synthesis of enantiomerically pure hyperjapones H and I and comparison of their optical rotations to those of the natural samples indicated that these meroterpenoids are probably biosynthesised as either racemic or scalemic mixtures. | - |
dc.description.statementofresponsibility | Hiu C. Lam, Quang D. Phan, Christopher J. Sumby, and Jonathan H. George | - |
dc.language.iso | en | - |
dc.publisher | CSIRO Publishing | - |
dc.rights | Journal compilation © CSIRO 2018 | - |
dc.source.uri | http://dx.doi.org/10.1071/ch18141 | - |
dc.title | Biomimetic synthesis of hyperjapones F-I | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1071/CH18141 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP160103393 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FT170100437 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Sumby, C. [0000-0002-9713-9599] | - |
dc.identifier.orcid | George, J. [0000-0002-7330-2160] | - |
Appears in Collections: | Aurora harvest 8 Chemistry publications |
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