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https://hdl.handle.net/2440/116514
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dc.contributor.author | Chen, G.-F. | - |
dc.contributor.author | Cao, X. | - |
dc.contributor.author | Wu, S. | - |
dc.contributor.author | Zeng, X. | - |
dc.contributor.author | Ding, L.-X. | - |
dc.contributor.author | Zhu, M. | - |
dc.contributor.author | Wang, H. | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2017; 139(29):9771-9774 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.issn | 1520-5126 | - |
dc.identifier.uri | http://hdl.handle.net/2440/116514 | - |
dc.description.abstract | We report the discovery of a dramatically enhanced N2 electroreduction reaction (NRR) selectivity under ambient conditions via the Li+ incorporation into poly(N-ethyl-benzene-1,2,4,5-tetracarboxylic diimide) (PEBCD) as a catalyst. The detailed electrochemical evaluation and density functional theory calculations showed that Li+ association with the O atoms in the PEBCD matrix can retard the HER process and can facilitate the adsorption of N2 to afford a high potential scope for the NRR process to proceed in the "[O-Li+]·N2-Hx" alternating hydrogenation mode. This atomic-scale incorporation strategy provides new insight into the rational design of NRR catalysts with higher selectivity. | - |
dc.description.statementofresponsibility | Gao-Feng Chen, Xinrui Cao, Shunqing Wu, Xingye Zeng, Liang-Xin Ding, Min Zhu and Haihui Wang | - |
dc.language.iso | en | - |
dc.publisher | ACS Publishing | - |
dc.rights | © 2017 American Chemical Society | - |
dc.source.uri | http://dx.doi.org/10.1021/jacs.7b04393 | - |
dc.title | Ammonia electrosynthesis with high selectivity under ambient conditions via a Li+ incorporation strategy | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/jacs.7b04393 | - |
dc.relation.grant | 21406078 | - |
dc.relation.grant | 51621001 | - |
pubs.publication-status | Published | - |
Appears in Collections: | Aurora harvest 3 Chemistry publications |
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