Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/116668
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wen, T. | - |
dc.contributor.author | Zheng, Y. | - |
dc.contributor.author | Xu, C. | - |
dc.contributor.author | Zhang, J. | - |
dc.contributor.author | Jaroniec, M. | - |
dc.contributor.author | Qiao, S.-Z. | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Materials horizons, 2018; 5(6):1152-1155 | - |
dc.identifier.issn | 2051-6347 | - |
dc.identifier.issn | 2051-6355 | - |
dc.identifier.uri | http://hdl.handle.net/2440/116668 | - |
dc.description.abstract | A new alkaline-stable anionic boron imidazolate framework, CdB(im)4(btec)0.5·H2O (BIF-89, im = imidazolate, btec = benzene-1,2,4,5-tetracarboxylate), was designed and synthesized. The resulting BIF-89 with a three-dimensional molecular structure exhibits a unique mechanochromic behavior with a maximum emission blue shift of about 23 nm in the blue emitting range. Additionally, the uncoordinated carboxylic groups in the BIF-89 framework can stabilize incorporation of Fe(III) at the atomic level to form Fe-immobilized BIF-89 (Fe@BIF-89), which can serve as an effective electrocatalyst for the oxygen evolution reaction in strongly alkaline media. The new BIF-89 expands the field of MOFs to luminescence mechanochromism and electrocatalytic applications without involving precious metals. | - |
dc.description.statementofresponsibility | Tian Wen, Yao Zheng, Chaochen Xu, Jian Zhang, Mietek Jaroniec and Shi-Zhang Qiao | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry | - |
dc.rights | This journal is ©The Royal Society of Chemistry 2018 | - |
dc.source.uri | http://dx.doi.org/10.1039/c8mh00859k | - |
dc.title | A boron imidazolate framework with mechanochromic and electrocatalytic properties | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/C8MH00859K | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FL170100154 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DE160101163 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP170104464 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP160104866 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Zheng, Y. [0000-0002-2411-8041] | - |
dc.identifier.orcid | Xu, C. [0000-0001-9988-0447] | - |
dc.identifier.orcid | Qiao, S.-Z. [0000-0002-1220-1761] [0000-0002-4568-8422] | - |
Appears in Collections: | Aurora harvest 8 Chemistry and Physics publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.