Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/116668
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dc.contributor.authorWen, T.en
dc.contributor.authorZheng, Y.en
dc.contributor.authorXu, C.en
dc.contributor.authorZhang, J.en
dc.contributor.authorJaroniec, M.en
dc.contributor.authorQiao, S.-.Z.en
dc.date.issued2018en
dc.identifier.citationMaterials Horizons, 2018; 5(6):1152-1155en
dc.identifier.issn2051-6347en
dc.identifier.issn2051-6355en
dc.identifier.urihttp://hdl.handle.net/2440/116668-
dc.description.abstractA new alkaline-stable anionic boron imidazolate framework, CdB(im)4(btec)0.5·H2O (BIF-89, im = imidazolate, btec = benzene-1,2,4,5-tetracarboxylate), was designed and synthesized. The resulting BIF-89 with a three-dimensional molecular structure exhibits a unique mechanochromic behavior with a maximum emission blue shift of about 23 nm in the blue emitting range. Additionally, the uncoordinated carboxylic groups in the BIF-89 framework can stabilize incorporation of Fe(III) at the atomic level to form Fe-immobilized BIF-89 (Fe@BIF-89), which can serve as an effective electrocatalyst for the oxygen evolution reaction in strongly alkaline media. The new BIF-89 expands the field of MOFs to luminescence mechanochromism and electrocatalytic applications without involving precious metals.en
dc.description.statementofresponsibilityTian Wen, Yao Zheng, Chaochen Xu, Jian Zhang, Mietek Jaroniec and Shi-Zhang Qiaoen
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.rightsThis journal is ©The Royal Society of Chemistry 2018en
dc.titleA boron imidazolate framework with mechanochromic and electrocatalytic propertiesen
dc.typeJournal articleen
dc.identifier.rmid0030102317en
dc.identifier.doi10.1039/C8MH00859Ken
dc.relation.granthttp://purl.org/au-research/grants/arc/FL170100154en
dc.relation.granthttp://purl.org/au-research/grants/arc/DE160101163en
dc.relation.granthttp://purl.org/au-research/grants/arc/DP170104464en
dc.relation.granthttp://purl.org/au-research/grants/arc/DP160104866en
dc.identifier.pubid438656-
pubs.library.collectionChemistry and Physics publicationsen
pubs.library.teamDS10en
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
dc.identifier.orcidZheng, Y. [0000-0002-2411-8041]en
dc.identifier.orcidXu, C. [0000-0001-9988-0447]en
Appears in Collections:Chemistry and Physics publications

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