Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/118370
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Type: Journal article
Title: Defining IOCG signatures through compositional data analysis: a case study of lithogeochemical zoning from the Olympic Dam deposit, South Australia
Author: Dmitrijeva, M.
Ehrig, K.
Ciobanu, C.
Cook, N.
Verdugo-Ihl, M.R.
Metcalfe, A.
Citation: Ore Geology Reviews, 2019; 105:86-101
Publisher: Elsevier
Issue Date: 2019
ISSN: 0169-1368
1872-7360
Statement of
Responsibility: 
Marija Dmitrijeva, Kathy J. Ehrig, Cristiana L. Ciobanu, Nigel J. Cook, Max R. Verdugo-Ihl, Andrew V. Metcalfe
Abstract: The Olympic Dam Cu-U-Au-Ag deposit is dominantly composed of mineralised hematite-breccias and occurs entirely within the Roxby Downs Granite. Multivariate statistical analysis of a large whole-rock, 15 m-interval geochemical dataset (10,565 samples) was undertaken to identify geochemical signatures characteristic of iron-oxide copper gold (IOCG)-style mineralization and constrain the conspicuous lithogeochemical zonation observed at Olympic Dam. Statistical analyses include principal component analysis on centred logratio (clr)-transformed data coupled with hierarchical clustering. Certain groups of elements that can be interpreted in terms of an evolving hydrothermal system relative to host lithologies are derived from data analysis: granitophile (U-W-Sn-Mo); siderophile (Ni-Co); chalcophile (Ag-Bi) and related elements (As-Sb and Au-Te). The distributions of elements within each group are investigated through three vertical cross-sections and are compared with known lithological and Cu-(Fe)-sulphide zonation. Throughout the Olympic Dam Breccia Complex, the IOCG signature is defined by multi-element combinations of the commodity metals Cu, U, Au, and Ag, coupled with a range of trace elements. Overall, the IOCG signature overlaps well with Fe-metasomatism despite mismatch which is likely due to discrete styles of mineralisation found only on the margins of the deposit and also to the presence of mineralised domains within Fe-poor zones. The IOCG signature is composed of two geochemical associations, which exhibit distinct spatial distributions. The first group, Cu-U3O8-Se-S, shows concentric zonation whereas the second group, Au-W-Mo-Sb-As, forms a vertical ∼1800 m deep corridor in the southeastern lobe of the deposit. The specific Au-W-Mo-As-Sb signature could potentially be generic within IOCG systems across the Olympic Cu-Au province and if so, would provide a proxy model for near-mine exploration.
Keywords: Principal component analysis; hierarchical clustering; whole-rock dataset; IOCG deposits; lithogeochemical zoning; Olympic Dam
Rights: © 2018 Elsevier B.V. All rights reserved.
RMID: 0030106081
DOI: 10.1016/j.oregeorev.2018.12.013
Grant ID: http://purl.org/au-research/grants/arc/IH130200033
Appears in Collections:Geology & Geophysics publications

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