Adelaide Research & Scholarship
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https://hdl.handle.net/2440/131025
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| Type: | Journal article |
| Title: | Biomimetic total synthesis of the rubiginosin meroterpenoids |
| Author: | Burchill, L. Day, A.J. Yahiaoui, O. George, J.H. |
| Citation: | Organic Letters, 2021; 23(2):578-582 |
| Publisher: | American Chemical Society |
| Issue Date: | 2021 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Laura Burchill, Aaron J. Day, Oussama Yahiaoui, and Jonathan H. George |
| Abstract: | Total synthesis of the <i>Rhododendron</i> meroterpenoids rubiginosins A and G, which both contain unusual 6-6-6-4 ring systems, has been achieved using a bioinspired cascade approach. Stepwise synthesis of these natural products, and the related 6-6-5-4 meroterpenoids fastinoid B and rhodonoid B, from naturally occurring chromene precursors is also reported. |
| Keywords: | Rhododendron Terpenes Benzopyrans Biological Products Biomimetics Molecular Structure |
| Rights: | © 2020 American Chemical Society |
| DOI: | 10.1021/acs.orglett.0c04117 |
| Grant ID: | http://purl.org/au-research/grants/arc/DP200102964 http://purl.org/au-research/grants/arc/DP200102964 |
| Published version: | http://dx.doi.org/10.1021/acs.orglett.0c04117 |
| Appears in Collections: | Aurora harvest 8 Chemistry publications |
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