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Type: Journal article
Title: Templated synthesis of zirconium(IV)-based metal-organic layers (MOLs) with accessible chelating sites
Author: Gimeno-Fonquernie, P.
Liang, W.
Albalad, J.
Kuznicki, A.
Price, J.R.
Bloch, E.D.
Doonan, C.J.
Sumby, C.J.
Citation: Chemical Communications, 2022; 58(7):957-960
Publisher: Royal Society of Chemistry
Issue Date: 2022
ISSN: 1359-7345
Statement of
Pol Gimeno-Fonquernie, Weibin Liang, Jorge Albalad, Andrew Kuznicki, Jason R. Price, Eric D. Bloch, Christian J. Doonan and Christopher J. Sumby
Abstract: Metal-organic layers (MOLs) are of great interest in heterogeneous catalysis, particularly materials that can accommodate extraneous metal centres. Here, we demonstrate a two-step preorganisation/delamination synthetic strategy using CuI as a template to prepare Zr-based MOLs with accessible 'syn' bis-pyrazolyl chelating sites (named UAM-2·ns) that are poised for quantitative post-synthetic metalation with late transition metals.
Description: First published 17 Dec 2021
Rights: This journal is © The Royal Society of Chemistry 2021.
DOI: 10.1039/d1cc06443f
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Appears in Collections:Chemistry publications

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