Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/136081
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Type: | Journal article |
Title: | Post-Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete Co₂₄ Organometallic Complex** |
Other Titles: | Post-Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete C024 Organometallic Complex** |
Author: | Thomas, C.M. Liang, W. Preston, D. Doonan, C.J. White, N.G. |
Citation: | Chemistry: A European Journal, 2022; 28(51):1-7 |
Publisher: | Wiley |
Issue Date: | 2022 |
ISSN: | 0947-6539 1521-3765 |
Statement of Responsibility: | Chriso M. Thomas, Weibin Liang, Dan Preston, Christian J. Doonan, and Nicholas G. White |
Abstract: | A new alkyne-based hydrocarbon cage was synthesized in high overall yield using alkyne-alkyne coupling in the cage forming step. The cage is porous and displays a moderately high BET surface area (546 m2 g−1). The cage loses crystallinity on activation and thus is porous in its amorphous form, while very similar cages have been either non-porous, or retained crystallinity on activation. Reaction of the cage with Co2(CO)8 results in exhaustive metalation of its 12 alkyne groups to give the Co24(CO)72 adduct of the cage in good yield. |
Keywords: | alkynes cages cobalt porosity post-synthetic modification |
Description: | First published: 21 July 2022 |
Rights: | © 2022 The Authors.Chemistry- A European Journal published by Wiley-VCHGmbH.This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original workis properly cited,the use is non-commercial and no modifications or adaptations are made. |
DOI: | 10.1002/chem.202200958 |
Grant ID: | http://purl.org/au-research/grants/arc/FT210100495 |
Published version: | http://dx.doi.org/10.1002/chem.202200958 |
Appears in Collections: | Chemistry publications |
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hdl_136081.pdf | Published version | 951.99 kB | Adobe PDF | View/Open |
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