Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/136973
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Type: Journal article
Title: Absorbance-transmission and fluorescence excitation-emission matrix (A-TEEM) with multi-block data analysis and machine learning for accurate intraregional classification of Barossa Shiraz wine
Author: Ranaweera, R.K.R.
Bastian, S.E.P.
Gilmore, A.M.
Capone, D.L.
Jeffery, D.W.
Citation: Food Control, 2023; 144:1-8
Publisher: Elsevier
Issue Date: 2023
ISSN: 0956-7135
1873-7129
Statement of
Responsibility: 
Ranaweera K.R. Ranaweera, Susan E.P. Bastian, Adam M. Gilmore, Dimitra L. Capone, David W. Jeffery
Abstract: Authentication of wine can be considered at different scales, with classification according to country, province/ state, or appellation/wine producing region. An absorbance-transmission and excitation-emission matrix (ATEEM) technique was applied for the first time to examine intraregional differences, using Shiraz wines (n = 186) produced during three vintages from five subregions of Barossa Valley and from Eden Valley. Absorption spectra and EEM fingerprints were modelled as a multi-block data set for initial exploration with k-means cluster analysis and principal component analysis, and then with machine learning modelling using extreme gradient boosting discriminant analysis (XGBDA). Whereas some clustering was evident with the initial unsupervised approaches, classification with XGBDA afforded an impressive 100% correct class assignment for subregion and vintage year. Extending the utility and novelty of the A-TEEM approach, predictive models for chemical parameters (alcohol, glucose + fructose, pH, titratable acidity, and volatile acidity) were also validated using ATEEM data with XGB regression.
Keywords: Extreme gradient boosting; Terroir; Subregion; Authentication; Provenance
Description: Available online 26 August 2022
Rights: © 2022 Elsevier Ltd. All rights reserved.
DOI: 10.1016/j.foodcont.2022.109335
Grant ID: http://purl.org/au-research/grants/arc/IC170100008
Published version: http://dx.doi.org/10.1016/j.foodcont.2022.109335
Appears in Collections:Agriculture, Food and Wine publications
ARC Training Centre for Innovative Wine Production publications

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