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Type: Journal article
Title: Cluster-containing carbon-rich molecules: reactions of ruthenium cluster carbonyls with {Au(PR₃)}₂(μ-C≡CC≡C) (R = Ph, tol)
Other Titles: Cluster-containing carbon-rich molecules: reactions of ruthenium cluster carbonyls with {Au(PR(3))}(2)(mu-Ctriple barCCtriple barC) (R = Ph, tol)
Author: Bruce, M.
Zaitseva, N.
Skelton, B.
White, A.
Citation: Journal of Organometallic Chemistry, 2005; 690(13):3268-3277
Publisher: Elsevier Science Sa
Issue Date: 2005
ISSN: 0022-328X
Statement of
Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White
Abstract: Complexes containing C4 ligands attached to one or two AuRu3 clusters by conventional σ, 2π interactions have been obtained from reactions between (R3P)AuC≡CC≡CAu(PR3) (R = Ph, tol) or Au(C≡CC≡CH){P(tol)3} and either Ru3(CO)12, Ru3(CO)10(NCMe)2 or Ru3(μ-dppm)(CO)10. The X-ray determined structures of {(R3P)AuRu3(CO)9}2(μ3,η2:μ3,η2-C2C2) [R = Ph (1) (three solvates), tol (2)], AuRu3{μ3,η2-C2C≡CAu(PPh3)}(CO)9(PPh3) (3) and {(Ph3P)AuRu3(μ-dppm)(CO)7} (μ3,η2:μ3,η2-C2C2){Ru3(μ-H)(μ-dppm)(CO)7} (4) are reported.
RMID: 0020050573
DOI: 10.1016/j.jorganchem.2005.04.010
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Appears in Collections:Chemistry publications

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