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https://hdl.handle.net/2440/17794
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Type: | Journal article |
Title: | Cluster-containing carbon-rich molecules: reactions of ruthenium cluster carbonyls with {Au(PR₃)}₂(μ-C≡CC≡C) (R = Ph, tol) |
Other Titles: | Cluster-containing carbon-rich molecules: reactions of ruthenium cluster carbonyls with {Au(PR(3))}(2)(mu-Ctriple barCCtriple barC) (R = Ph, tol) |
Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
Citation: | Journal of Organometallic Chemistry, 2005; 690(13):3268-3277 |
Publisher: | Elsevier Science Sa |
Issue Date: | 2005 |
ISSN: | 0022-328X |
Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
Abstract: | Complexes containing C4 ligands attached to one or two AuRu3 clusters by conventional σ, 2π interactions have been obtained from reactions between (R3P)AuC≡CC≡CAu(PR3) (R = Ph, tol) or Au(C≡CC≡CH){P(tol)3} and either Ru3(CO)12, Ru3(CO)10(NCMe)2 or Ru3(μ-dppm)(CO)10. The X-ray determined structures of {(R3P)AuRu3(CO)9}2(μ3,η2:μ3,η2-C2C2) [R = Ph (1) (three solvates), tol (2)], AuRu3{μ3,η2-C2C≡CAu(PPh3)}(CO)9(PPh3) (3) and {(Ph3P)AuRu3(μ-dppm)(CO)7} (μ3,η2:μ3,η2-C2C2){Ru3(μ-H)(μ-dppm)(CO)7} (4) are reported. |
DOI: | 10.1016/j.jorganchem.2005.04.010 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
Published version: | http://dx.doi.org/10.1016/j.jorganchem.2005.04.010 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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