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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/17903
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dc.contributor.authorBruce, M.-
dc.contributor.authorSmith, M.-
dc.contributor.authorZaitseva, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.date.issued2003-
dc.identifier.citationJournal of Organometallic Chemistry, 2003; 670(1-2):170-177-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2440/17903-
dc.descriptionCopyright © 2003 Elsevier Science B.V.-
dc.description.abstractReactions of Co3(μ3-CBr)(μ-dppm)(CO)7 with {Au[P(tol)3]}2{μ-(C6-point triple bond; length half of m-dashC)n} (n=2–4) have given {Co3(μ-dppm)(CO)7}{μ3:μ3-C(C6-point triple bond; length half of m-dashC)nC} [n=2 (1), 3 (2), 4 (3)] containing carbon chains capped by the cobalt clusters. Tetracyanoethene reacts with 2 to give {Co3(μ-dppm)(CO)7}2{μ3:μ3-C(C6-point triple bond; length half of m-dashC)2C[=C(CN)2]C[=C(CN)2]C} (4). X-ray structural characterisation of 1, 3 and 4 are reported, that for 3 being the first of a cluster-capped C10 chain.-
dc.description.statementofresponsibilityMichael I. Bruce, Mark E. Smith, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White-
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description-
dc.language.isoen-
dc.publisherElsevier Science Sa-
dc.source.urihttp://dx.doi.org/10.1016/s0022-328x(02)02186-1-
dc.subjectCarbon chains-
dc.subjectCobalt clusters-
dc.subjectCapped clusters-
dc.subjectC10 chains-
dc.titleA new approach to the synthesis of carbon chains capped by metal clusters-
dc.typeJournal article-
dc.identifier.doi10.1016/S0022-328X(02)02186-1-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 2
Chemistry publications

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