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Type: Journal article
Title: Syntheses and crystal structures of some CCo3 clusters containing PPh3 or dppm Ligands
Author: Bruce, M.
Kramarczuk, K.
Perkins, G.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Journal of Cluster Science, 2004; 15(2):119-137
Publisher: Kluwer Academic/Plenum Publ
Issue Date: 2004
ISSN: 1040-7278
Statement of
Michael I. Bruce, Kathy A. Kramarczuk, Gary J. Perkins, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Abstract: Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.
Keywords: cobalt carbide clusters; X-ray structures; tertiary phosphine complexes; amido; carboxylate
Description: The original publication is available at
RMID: 0020040414
DOI: 10.1023/B:JOCL.0000027397.89365.42
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Appears in Collections:Chemistry publications

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