Adelaide Research & Scholarship
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https://hdl.handle.net/2440/17977
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| Type: | Journal article |
| Title: | Preparation and molecular structure of Hg{CºCCºC[Ru(dppe)Cp*]}2-non-linearity in a molecular rod |
| Other Titles: | Preparation and molecular structure of Hg{CoCCoC[Ru(dppe)Cp*]}2-non-linearity in a molecular rod |
| Author: | Bruce, M. Halet, J. Le Guennic, B. Skelton, B. Smith, M. White, A. |
| Citation: | Inorganica Chimica Acta, 2003; 350:175-181 |
| Publisher: | Elsevier Science SA |
| Issue Date: | 2003 |
| ISSN: | 0020-1693 1873-3255 |
| Statement of Responsibility: | Michael I. Bruce, Jean-François Halet, Boris Le Guennica, Brian W. Skelton, Mark E. Smith and Allan H. White |
| Abstract: | The preparations of Hg{CCCC[Ru(PR3)2Cp′]}2 [(PR3)2=dppe, Cp′=Cp*, 1; PR3=PPh3, Cp′=Cp, 2] are reported and the molecular structure of 1 is described. Following the observation of an unusually large bending at the carbon atoms attached to mercury [C(3)---C(4)---Hg 166.5(3)°]. DFT calculations were employed to probe its electronic structure. The system exhibits a closed-shell electronic configuration and the bending must be ascribed to low-energy lattice forces. |
| Rights: | Copyright © 2003 Elsevier Science B.V. All rights reserved. |
| DOI: | 10.1016/S0020-1693(02)01543-8 |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#description |
| Published version: | http://dx.doi.org/10.1016/s0020-1693(02)01543-8 |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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