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https://hdl.handle.net/2440/17980
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Humphrey, P. | - |
dc.contributor.author | Okucu, S. | - |
dc.contributor.author | Schmutzler, R. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 2004 | - |
dc.identifier.citation | Inorganica Chimica Acta, 2004; 357(6):1805-1812 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.issn | 1873-3255 | - |
dc.identifier.uri | http://hdl.handle.net/2440/17980 | - |
dc.description.abstract | Reactions between Ru3(CO)12 and 1,8- bis(diphenylphosphino)naphthalene (dppn) have given the four complexes Ru 3(μ-H){μ3-PPh2(nap)PPh(C 6H4)}(CO)8 (1), Ru4(μ-H) {μ3-PPh2(nap)PPh(C6H4)}(μ-CO) 3(CO)7 (2) and Ru4(μ-H)(μ3- C6H4){μ-PPh(nap)PPh2}(CO)11 (3) (in refluxing thf), and Ru4{μ4-P(nap)PPh 2}(μ4-C6H4)(μ-CO)(CO) 9 (4) (in refluxing toluene) which have been characterised by single crystal X-ray studies. They have been formed by aryl C-H and aryl C-P bond cleavage reactions, presumably from an initial (unobserved) chelate dppn complex. The unchanged chelating ligand is found in Ru3(μ-dppm) (CO)8(dppn) (5), obtained from Ru3(μ-dppm)(CO) 10 and dppn in refluxing thf. © 2004 Elsevier B.V. All rights reserved. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Paul A. Humphrey, Sakir Okucu, Reinhard Schmutzler, Brian W. Skelton and Allan H. White | - |
dc.description.uri | http://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#description | - |
dc.language.iso | en | - |
dc.publisher | Elsevier Science SA | - |
dc.source.uri | http://dx.doi.org/10.1016/j.ica.2004.01.022 | - |
dc.title | Reactions of 1,8-bis(diphenylphosphino)naphthalene with ruthenium cluster carbonyls: C-H and C-P bond cleavage reactions | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/j.ica.2004.01.022 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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