Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/22942
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Type: Journal article
Title: Effect of cation vacancy and crystal superstructure on thermodynamics or iron monosulfides
Author: Wang, H.
Pring, A.
Wu, F.
Chen, G.
Jiang, J.
Xia, F.
Zhang, J.
Ngothai, Y.
O'Neill, B.
Citation: Journal of Sulfur Chemistry, 2006; 27(3):271-282
Publisher: Taylor & Francis
Issue Date: 2006
ISSN: 1741-5993
1741-6000
Statement of
Responsibility: 
Yung My Ngothai; Haipeng Wang; Allan Pring; Fei Wu; Guorong Chen; Jianhua Jiang; Fang Xia; Jian Zhang; Brian O'neill
Abstract: Iron monosulfides, Fe1 - xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1 - xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.
Keywords: Iron monosulfide
Vacancy
Nonstoichiometry
Pyrrhotite
DOI: 10.1080/17415990600646124
Published version: http://dx.doi.org/10.1080/17415990600646124
Appears in Collections:Aurora harvest 2
Chemical Engineering publications

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