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https://hdl.handle.net/2440/22942
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Type: | Journal article |
Title: | Effect of cation vacancy and crystal superstructure on thermodynamics or iron monosulfides |
Author: | Wang, H. Pring, A. Wu, F. Chen, G. Jiang, J. Xia, F. Zhang, J. Ngothai, Y. O'Neill, B. |
Citation: | Journal of Sulfur Chemistry, 2006; 27(3):271-282 |
Publisher: | Taylor & Francis |
Issue Date: | 2006 |
ISSN: | 1741-5993 1741-6000 |
Statement of Responsibility: | Yung My Ngothai; Haipeng Wang; Allan Pring; Fei Wu; Guorong Chen; Jianhua Jiang; Fang Xia; Jian Zhang; Brian O'neill |
Abstract: | Iron monosulfides, Fe1 - xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1 - xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed. |
Keywords: | Iron monosulfide Vacancy Nonstoichiometry Pyrrhotite |
DOI: | 10.1080/17415990600646124 |
Published version: | http://dx.doi.org/10.1080/17415990600646124 |
Appears in Collections: | Aurora harvest 2 Chemical Engineering publications |
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