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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/23525
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dc.contributor.authorAntonova, A.-
dc.contributor.authorBruce, M.-
dc.contributor.authorHumphrey, P.-
dc.contributor.authorGaudio, M.-
dc.contributor.authorNicholson, B.-
dc.contributor.authorScoleri, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.contributor.authorZaitseva, N.-
dc.date.issued2006-
dc.identifier.citationJournal of Organometallic Chemistry, 2006; 691(22):4694-4707-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2440/23525-
dc.description.abstractA series of alkynyl-tricobalt carbonyl clusters, Co3(μ3-CnR)(μ-dppm)(CO)7 [R = But, Ph, C6H4I, C6H4CCPh, SiMe3, Fc, Au(PPh3)] containing three, five or seven carbons in the chain, have been prepared by elimination of phosphine–gold(I) halides in reactions between Co3(μ3-CBr)(μ-dppm)(CO)7 and Au(CCR)(PPh3) or between Co3{μ3-CCCAu(PR3)} (μ-dppm)(CO)7 (R = Ph, tol) and ICCR′ (R′ = SiMe3, Fc). The use of poly-substituted arenes or ferrocenes has enabled preparation of the complexes 1,4-{(OC)7(μ-dppm)Co3 (μ3-CCC)}2C6H3X-5 (X = H, Br), 1,3,5-{(OC)7(μ-dppm)Co3(μ3-CCC)}3C6H3 and 1,1′-{(OC)7(μ-dppm)Co3 (μ3-CCC)}2Fc′ [Fc′ = Fe(η-C5H4-)2]. The X-ray determined molecular structures of 12 of the complexes are reported.-
dc.description.statementofresponsibilityAlla B. Antonova, Michael I. Bruce, Paul A. Humphrey, Maryka Gaudio, Brian K. Nicholson, Nancy Scoleri, Brian W. Skelton, Allan H. Whited and Natasha N. Zaitseva-
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description-
dc.language.isoen-
dc.publisherElsevier Science Sa-
dc.source.urihttp://dx.doi.org/10.1016/j.jorganchem.2006.08.004-
dc.subjectCarbon-tricobalt cluster-
dc.subjectAlkyne-
dc.subjectPoly-yne-
dc.subjectX-ray structure-
dc.subjectGold-
dc.titleAlkynyl and poly-ynyl derivatives of carbon-tricobalt clusters-
dc.typeJournal article-
dc.identifier.doi10.1016/j.jorganchem.2006.08.004-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
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Chemistry publications

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