Adelaide Research & Scholarship
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https://hdl.handle.net/2440/34470
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| Type: | Journal article |
| Title: | A Convenient Method for the Synthesis of Dehydroquinic Acid |
| Author: | Le Sann, C. Abell, C. Abell, A. |
| Citation: | Synthetic Communications: an international journal for rapid communication of synthetic organic chemistry, 2003; 33(4):527-533 |
| Publisher: | Marcel Dekker Inc |
| Issue Date: | 2003 |
| ISSN: | 0039-7911 1532-2432 |
| Statement of Responsibility: | Christine Le Sann; Chris Abell; Andrew D. Abell |
| Abstract: | A convenient synthesis of dehydroquinic acid and its corresponding methyl ester are described. Protection of the trans diol of quinic acid, followed by PCC oxidation, gave fully protected dehydroquinic acid. This gave methyl dehydroquinate on mild acid catalyzed hydrolysis. Ester hydrolysis then gave potassium dehydroquinate which was treated with amberlite to afford dehydroquinic acid. |
| Keywords: | Shikimate pathway Dehydroquinic acid Synthesis Selective protection |
| DOI: | 10.1081/SCC-120015805 |
| Published version: | http://dx.doi.org/10.1081/scc-120015805 |
| Appears in Collections: | Aurora harvest Chemistry publications |
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