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Type: Journal article
Title: Syntheses and molecular structures of Ru₃(µ-H)(µ₃-CPh₂CCC≡CPh)(CO)₉ and Ru₃{µ₃-CPhCHCC(=CPh₂)CH=CPh}(µ-CO)(CO)₈
Other Titles: Syntheses and molecular structures of Ru3(mu-H)(mu3-CPh2CCC triple bar CPh)(CO)9 and Ru3{mu3-CPhCHCC(=CPh2)CH=CPh}(mu-CO)(CO)8
Author: Bruce, M.
Meier, A.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Journal of Organometallic Chemistry, 2004; 689(5):965-970
Publisher: Elsevier Science Sa
Issue Date: 2004
ISSN: 0022-328X
Statement of
Michael I. Bruce, Andrew C. Meier, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Abstract: The reaction between Ru3(μ-H){μ3-C2CPh2(OH)}(CO)9 and HCCPh, carried out in the presence of HBF4 · Me2O, afforded the cluster complexes Ru3(μ-H)(μ3-CPh2CCCCPh)(CO)9 (5) and Ru3{μ3-CPhCHCC(=CPh2)CH=CPh}(μ-CO)(CO)8 (6), both of which were characterised by single-crystal X-ray studies.
Keywords: Author Keywords: Ruthenium; Clusters; Reactions with alkynes; Allenylidene
RMID: 0020040217
DOI: 10.1016/j.jorganchem.2003.12.031
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Appears in Collections:Chemistry publications

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