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https://hdl.handle.net/2440/39202
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Type: | Journal article |
Title: | Syntheses and molecular structures of Ru₃(µ-H)(µ₃-CPh₂CCC≡CPh)(CO)₉ and Ru₃{µ₃-CPhCHCC(=CPh₂)CH=CPh}(µ-CO)(CO)₈ |
Other Titles: | Syntheses and molecular structures of Ru3(mu-H)(mu3-CPh2CCC triple bar CPh)(CO)9 and Ru3{mu3-CPhCHCC(=CPh2)CH=CPh}(mu-CO)(CO)8 |
Author: | Bruce, M. Meier, A. Skelton, B. White, A. Zaitseva, N. |
Citation: | Journal of Organometallic Chemistry, 2004; 689(5):965-970 |
Publisher: | Elsevier Science Sa |
Issue Date: | 2004 |
ISSN: | 0022-328X |
Statement of Responsibility: | Michael I. Bruce, Andrew C. Meier, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | The reaction between Ru3(μ-H){μ3-C2CPh2(OH)}(CO)9 and HCCPh, carried out in the presence of HBF4 · Me2O, afforded the cluster complexes Ru3(μ-H)(μ3-CPh2CCCCPh)(CO)9 (5) and Ru3{μ3-CPhCHCC(=CPh2)CH=CPh}(μ-CO)(CO)8 (6), both of which were characterised by single-crystal X-ray studies. |
Keywords: | Author Keywords: Ruthenium Clusters Reactions with alkynes Allenylidene |
DOI: | 10.1016/j.jorganchem.2003.12.031 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
Published version: | http://dx.doi.org/10.1016/j.jorganchem.2003.12.031 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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