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Type: Journal article
Title: Reactions of {Ru₃(μ-PPh₂)(CO)9}₂(μ₃:μ₃-C₄) with H+/H- or H₂ to Yield Penta- and Hexa-Nuclear Cluster Compounds
Other Titles: Reactions of {Ru(3)(mu-PPh(2))(CO)9}(2)(mu(3):mu(3)-C(4)) with H+/H- or H(2) to Yield Penta- and Hexa-Nuclear Cluster Compounds
Author: Adams, C.
Bruce, M.
Humphrey, P.
Skelton, B.
White, A.
Citation: Australian Journal of Chemistry, 2001; 54(5):325-327
Publisher: CSIRO Publishing
Issue Date: 2001
ISSN: 0004-9425
Statement of
Chris J. Adams, Michael I. Bruce, Paul A. Humphrey, Brian W. Skelton and Allan H. White
Abstract: Addition of K[BHBus3] to {Ru3(µ-PPh2)(CO)9}2(µ3:µ3-C4) (1), followed by acidification, is proposed to give {Ru3H(µ-PPh2)(CO)9}2(µ3:µ3-C=CHCH=C) (2), in which hydrogen atoms have added to each cluster unit and to the C4 fragment of (1) to give a bis(vinylidene) ligand. The osmium analogue has also been prepared. In contrast, the reaction with dihydrogen results in the pentanuclear complex Ru3{µ3:µ-C2C2[Ru2(µ-PPh2)(CO)6]}(µ- PPh2)(CO)9 (3), by cleavage of an Ru(CO)3 fragment from (1).
Rights: © CSIRO 2001
RMID: 0020010302
DOI: 10.1071/CH01080
Published version:
Appears in Collections:Chemistry publications

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