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https://hdl.handle.net/2440/4368
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Type: | Journal article |
Title: | Binary and ternary metallo-b-cyclodextrins of 6A-[Bis(carboxylatomethyl)amino}-6A-deoxy-b-cyclodextrin |
Author: | Sandow, M. May, B. Easton, C. Lincoln, S. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 2000; 53(2):149-152 |
Publisher: | C S I R O Publishing |
Issue Date: | 2000 |
ISSN: | 0004-9425 |
Statement of Responsibility: | Melissa Sandow, Bruce L. May, Christopher J. Easton and Stephen F. Lincoln |
Abstract: | The binary metallo-β-cyclodextrins formed by 6A-[bis(carboxylatomethyl)amino]-6 A-deoxy-β-cyclodextrin ([M(βCDida)], where M2+ = Co2+, Ni2+, Cu2+ and Zn2+) are characterized by log(K/dm3 mol-1) = 7.29±0.01, 9.74± 0.02, 8.89±0.03 and 6.08±0.02, respectively, in aqueous solution at 298.2 K and I = 0.10 mol dm-3 (NaClO4), where K is the stability constant. The ternary metallo-β-cyclodextrins formed by [M(βCDida)] and (R)- and (S)-tryptophanate, [M(βCDida)(R)-Trp]- and [M(βCDida)(S)-Trp]-, are characterized by log(K/dm3 mol-1) = 5.49±0.04 and 5.16±0.07, 6.33±0.04 and 6.34±0.02, 6.91±0.02 and 6.99±0.01, and 5.34±0.02 and 5.36±0.04, respectively, when M2+ = Co2+, Ni2+, Cu2+ and Zn2+. For [M(βCDida)(R)-Trp]- and [M(βCDida)(S)-Trp]-, pKa values of 8.07±0.04 and 8.4±0.1, 7.45±0.02 and 7.88±0.04, 8.46±0.09 and 8.40±0.01, and 8.92±0.05 and 8.7±0.2 are found when M2+ = Co2+, Ni2+, Cu2+ and Zn2+, respectively, and are attributed to the protolysis of an aqua ligand occupying a sixth coordination site on M2+. © CSIRO 2000. |
Keywords: | Cyclodextrin host– guest complex imidodiacetate complexation |
Description: | Copyright © CSIRO 2000 |
DOI: | 10.1071/CH00001 |
Published version: | http://dx.doi.org/10.1071/ch00001 |
Appears in Collections: | Aurora harvest 2 Chemistry publications Environment Institute publications |
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