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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4384
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dc.contributor.authorBruce, M.-
dc.contributor.authorHumphrey, P.-
dc.contributor.authorWilliams, M.-
dc.date.issued1997-
dc.identifier.citationAustralian Journal of Chemistry: an international journal for chemical science, 1997; 50(12):1113-1117-
dc.identifier.issn0004-9425-
dc.identifier.urihttp://hdl.handle.net/2440/4384-
dc.description.abstract<jats:p> The reaction between Ru(O2CMe)2(PPh3)2 and HC5(CO2Me)5 affrded orange Ru(O2CMe)-{ C5(CO2Me)5}(PPh3)2, which on standing in methanolic solution in air lost PPh3 and was converted into purple {Ru(µO2CMe)[C5(CO2Me)5](PPh3)}2O. The C5(CO2Me)5 ligands chelate the ruthenium atoms via two ester carbonyl oxygens. The reaction of RuCl(O2CMe)(CO)(PPh3)2 with Tl[C5(CO2Me)5] in MeCN gave cream [Ru(O2CMe)(CO)(NCMe)(PPh3)2] [C5(CO2Me)5]. The syntheses of [C5(CO2Me)5]¯ salts of the [Ru(C=CHPh)(PPh3)2Cp]+, [Ru3H(CO)12]+, [Os(NCMe)(PPh3)2Cp]+, [OsH2(PPh3)2Cp]+ and [Re(CO)3(NCMe)3]+ cations are also reported.</jats:p>-
dc.language.isoen-
dc.publisherCSIRO Publishing-
dc.source.urihttp://dx.doi.org/10.1071/c97169-
dc.titlePentakis-methoxycarbonylcyclopentadiene chemistry. Some ruthenium, osmium and rhenium complexes-
dc.typeJournal article-
dc.identifier.doi10.1071/C97169-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 6
Chemistry publications

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