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https://hdl.handle.net/2440/4435
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DC Field | Value | Language |
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dc.contributor.author | Smyth, Douglas Robert | en |
dc.contributor.author | Hester, James | en |
dc.contributor.author | Young, Victor G. | en |
dc.contributor.author | Tiekink, Edward Richard Tom | en |
dc.date.issued | 2002 | en |
dc.identifier.citation | CrystEngComm, 2002; 4(86):517-521 | en |
dc.identifier.issn | 1466-8033 | en |
dc.identifier.uri | http://hdl.handle.net/2440/4435 | - |
dc.description.abstract | A common feature of the solid state structures of [(AuSC₆H₄{C(=O)Y}-2)₂(µ-dppf)], where dppf is bis(diphenylphosphine)ferrocene, and Y = OH (1), NH₂(2) and N(H)Me (3) is the formation of a chain motif. Association between the molecules is found to be highly dependent on the nature of Y so that in 1 only hydrogen bonding between molecules is observed. In 2, both hydrogen bonding and aurophilic interactions are found. By contrast, in 3 only aurophilic interactions contribute to the formation of the chain. These results are consistent with a similar energy of stabilisation and structure-directing propensity for the hydrogen bonding and aurophilic association operating in these systems. | en |
dc.description.statementofresponsibility | Douglas R. Smyth, James Hester, Victor G. Young, Jr and Edward R.T. Tiekink | en |
dc.language.iso | en | en |
dc.publisher | Royal Society of Chemistry | en |
dc.rights | © The Royal Society of Chemistry 2002 | en |
dc.title | Tuning aurophilic interactions in dinuclear phosphinegold(I) thiolates containing hydrogen bonding functionalities | en |
dc.type | Journal article | en |
dc.contributor.school | School of Chemistry and Physics | en |
dc.contributor.school | School of Chemistry and Physics : Chemistry | en |
dc.identifier.doi | 10.1039/b207045f | en |
Appears in Collections: | Chemistry publications |
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