Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4435
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dc.contributor.authorSmyth, Douglas Roberten
dc.contributor.authorHester, Jamesen
dc.contributor.authorYoung, Victor G.en
dc.contributor.authorTiekink, Edward Richard Tomen
dc.date.issued2002en
dc.identifier.citationCrystEngComm, 2002; 4(86):517-521en
dc.identifier.issn1466-8033en
dc.identifier.urihttp://hdl.handle.net/2440/4435-
dc.description.abstractA common feature of the solid state structures of [(AuSC₆H₄{C(=O)Y}-2)₂(µ-dppf)], where dppf is bis(diphenylphosphine)ferrocene, and Y = OH (1), NH₂(2) and N(H)Me (3) is the formation of a chain motif. Association between the molecules is found to be highly dependent on the nature of Y so that in 1 only hydrogen bonding between molecules is observed. In 2, both hydrogen bonding and aurophilic interactions are found. By contrast, in 3 only aurophilic interactions contribute to the formation of the chain. These results are consistent with a similar energy of stabilisation and structure-directing propensity for the hydrogen bonding and aurophilic association operating in these systems.en
dc.description.statementofresponsibilityDouglas R. Smyth, James Hester, Victor G. Young, Jr and Edward R.T. Tiekinken
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.rights© The Royal Society of Chemistry 2002en
dc.titleTuning aurophilic interactions in dinuclear phosphinegold(I) thiolates containing hydrogen bonding functionalitiesen
dc.typeJournal articleen
dc.contributor.schoolSchool of Chemistry and Physicsen
dc.contributor.schoolSchool of Chemistry and Physics : Chemistryen
dc.identifier.doi10.1039/b207045fen
Appears in Collections:Chemistry publications

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