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Type: Journal article
Title: Rearrangements of 1,3-diynes on ruthenium cluster carbonyls: isolation and structure of Ru6(PhCHC3C6H4)2(CO)15
Author: Bruce, M.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Inorganic Chemistry Communications, 1998; 1(4):134-136
Issue Date: 1998
ISSN: 1387-7003
Statement of
Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Abstract: Thermolysis of Ru3(μ3-PhC2C6-point triple bond; length half of m-dashCPh)(μ-CO)(CO)9 results in dimerisation, with concomitant internal cyclisation of the 1,3-diyne ligands to two methyleneindyne molecules which are attached in η2 and η4 modes to a novel Ru6 cluster core.
Keywords: Crystal structures; Ruthenium complexes; 1,3-Diyne complexes; Cluster complexes
RMID: 0030002863
DOI: 10.1016/S1387-7003(98)00035-5
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Appears in Collections:Chemistry publications

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