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https://hdl.handle.net/2440/4570
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Type: | Journal article |
Title: | Syntheses of complexes containing substituted 4-ethynylquinolines or 1-azabuta-1,3-dienes by addition of imines to a cationic butatrienylidene-ruthenium complex |
Author: | Bruce, M. Ke, M. Kelly, B. Low, P. Smith, M. Skelton, B. White, A. |
Citation: | Journal of Organometallic Chemistry, 1999; 599(2):184-201 |
Publisher: | Elsevier BV |
Issue Date: | 1999 |
ISSN: | 0022-328X |
Abstract: | Reactions of [Ru(=C=C=C=CH2)(PR3)2Cp]+ (R=Ph or OMe) with arylimines ArN=CH(C6H4R) afford either substituted quinolines, Ru{CCC9H4RN(Ar)}(PR3)2Cp, by attack of the terminal carbon of the butatrienylidene ligand at the imine carbon, followed by C-C bond formation between the ortho carbon of the N-aryl group and Cγ of the unsaturated carbene, or 1-azabuta-1,3-dienyl complexes, formed by cycloaddition of the N=CH group to Cγ=Cδ of the carbene, followed by opening of the resulting four-membered ring. Some product dependence on the nature of the substituents in the N- and C-aryl groups is found. The N atoms in the products are strongly basic, being readily protonated, methylated or aurated. The molecular structures of nine complexes are reported, together with that of a new modification of RuCl{P(OMe)3}2Cp. © 1999 Elsevier Science S.A. |
DOI: | 10.1016/S0022-328X(99)00456-8 |
Published version: | http://dx.doi.org/10.1016/s0022-328x(99)00456-8 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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