Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4644
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| Type: | Journal article |
| Title: | Helicity interchange in pendant arm tetraaza macrocyclic sodium(I) complexes |
| Author: | Dhillon, R. Stephens, A. Whitbread, S. Lincoln, S. Wainwright, K. |
| Citation: | Journal of the Chemical Society, Chemical Communications, 1995; 1(1):97-98 |
| Publisher: | The Society |
| Issue Date: | 1995 |
| ISSN: | 0022-4936 |
| Abstract: | The temperature dependent 13C NMR spectra of N,N′,N″,N‴-tetrakis(2-hydroxyethyl)-1,4,7, 10-tetraazacyclododecanesodium(I) and its 2-methoxyethyl and (S)-2-hydroxypropyl analogues are consistent with helicity interchange of the approximately square antiprismatic isomers occurring much more rapidly than the exchange of Na + between the solvated and complexed states in methanol in the first two cases, and moderately more so in the last case. |
| DOI: | 10.1039/C39950000097 |
| Published version: | http://dx.doi.org/10.1039/c39950000097 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications Environment Institute publications |
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