Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4654
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| Type: | Journal article |
| Title: | Coupling and disproportionation reactions of ethyne on ruthenium carbonyl clusters: Molecular structures of Ru5(m4-CHCHCCH2)(CO)15 and Ru6(m-H)(m4-C)(m4-CCMe)(m-CO)(CO)16 |
| Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
| Citation: | Journal- Chemical Society Dalton Transactions, 1999; 13-14(1):13-14 |
| Publisher: | Royal Society of Chemistry (RSC) |
| Issue Date: | 1999 |
| ISSN: | 0300-9246 1364-5447 |
| Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
| Abstract: | Thermolysis of Ru3(µ3-C2H2)(µ-CO)(CO)9 1 (50 °C, 6 h) has given Ru5(µ4-CHCHCCH2)(CO)15 3 and Ru6(µ-H)(µ4-C)(µ4-CCMe)(µ-CO)(CO)16 4, both characterised by X-ray crystallography; in 3, coupling of two ethyne molecules occurred, likely with prior isomerisation of one to vinylidene, whereas in 4, two molecules of ethyne disproportionate to carbide and methylethynyl. |
| DOI: | 10.1039/a807781i |
| Published version: | http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=a807781i |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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