Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/4719
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Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Dua, S. | - |
dc.contributor.author | Adams, G. | - |
dc.contributor.author | Sheldon, J. | - |
dc.contributor.author | Bowie, J. | - |
dc.date.issued | 1996 | - |
dc.identifier.citation | Journal of the Chemical Society, Perkin Transactions 2, 1996; 1(6):1251-1256 | - |
dc.identifier.issn | 1472-779X | - |
dc.identifier.issn | 1364-5471 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4719 | - |
dc.description.abstract | Certain anions X–⁻CH–CH₂–Y and X–CH₂⁻CH–Y interconvert under collisional activation conditions in the gas phase. Experiments designed to probe the mechanism(s) of particular interconversions suggest (i) that the ions MeO–CH₂–⁻CH–CN and MeO–⁻CH–CH₂–CN interconvert via 1,2 H transfer processes, and (ii) when X = Ph and Y = CO₂Me or CN, deuterium labelling and fragmentation data indicate that equilibration of Ph–⁻CHCH₂Y and PhCH₂–⁻CHY occurs, at least in part, by proton transfer to and from the phenyl ring. | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry | - |
dc.source.uri | http://dx.doi.org/10.1039/p29960001251 | - |
dc.title | Do carbanions undergo 1,2 hydrogen transfers in the gas phase? | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/P29960001251 | - |
pubs.publication-status | Published | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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