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Type: Journal article
Title: Unusual coupling of diynes and CO on an Ru3 cluster: crystal structure of Ru3{m3-CPhCC(O)C(SiMe3)C(C CSiMe3)CCPh}(m-dppm)(m-CO)(CO)6
Author: Bruce, M.
Zaitseva, N.
Skelton, B.
White, A.
Citation: Russian Chemical Bulletin, 1998; 47(5):983-987
Issue Date: 1998
ISSN: 1066-5285
Statement of
ruthenium; carbonyl clusters; alkyne complexes - diynes; silylalkynes - coupling of diynes and carbon monoxide
Abstract: Among several products isolated in the reaction between Ru3(μ3-PhC2C≡CPh)(μ-dppm)(CO)8 and Me3SiCэCCэCSiMe3 was the Ru3{μ3-CPhCC(O)C(SiMe3)C(C≡CSiMe3)CCPh)(μ-ddpm)(CO)7 complex formally obtained by coupling of the two diynes and a CO molecule on the Ru3 framework. Other products were Ru4(μ4-PhC2C≡CPh)(μ≡dppm)(CO)10 and the already known complex Ru3{μ3-PhCCHCC(C6H4}(μ-dppm)(CO)8.
RMID: 0030002887
DOI: 10.1007/BF02498172
Appears in Collections:Chemistry publications

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