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https://hdl.handle.net/2440/59443
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dc.contributor.author | Guo, X. | - |
dc.contributor.author | Wang, J. | - |
dc.contributor.author | Li, L. | - |
dc.contributor.author | Pham, D. | - |
dc.contributor.author | Clements, P. | - |
dc.contributor.author | Lincoln, S. | - |
dc.contributor.author | May, B. | - |
dc.contributor.author | Chen, Q. | - |
dc.contributor.author | Zheng, L. | - |
dc.contributor.author | Prud'homme, R. | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Journal of Polymer Science Part B: Polymer Physics, 2010; 48(16):1818-1825 | - |
dc.identifier.issn | 0887-6266 | - |
dc.identifier.issn | 1099-0488 | - |
dc.identifier.uri | http://hdl.handle.net/2440/59443 | - |
dc.description.abstract | A 1H NMR and rheological study of host-guest complexation interactions between three -cyclodextrin and three adamantyl substituted poly(acrylate)s, and also between them and adamantan-1-carboxylate and native -cyclodextrin, respectively, is reported. A close correllation between molecular level interactions and macroscopic characteristics of polymer networks in aqueous solution exists. It is found that intra- and intermolecular host-guest complexation between the host -cyclodextrin and guest adamantyl substituents and the length of the aliphatic tether between them and the poly(acrylate) backbone have important roles. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric interstrand linkage in polymer network formation. The preparations of five new 3% randomly substituted poly(acrylate)s are reported. | - |
dc.description.statementofresponsibility | Xuhong Guo, Jie Wang, Li Li, Duc-Truc Pham, Philip Clements, Stephen F. Lincoln, Bruce L. May, Qingchuan Chen, Li Zheng and Robert K. Prud'homme | - |
dc.language.iso | en | - |
dc.publisher | John Wiley & Sons Inc | - |
dc.rights | © 2010 Wiley Periodicals | - |
dc.source.uri | http://dx.doi.org/10.1002/polb.22052 | - |
dc.subject | b-cyclodextrin | - |
dc.subject | host-guest complexation | - |
dc.subject | NMR | - |
dc.subject | poly(acrylate) | - |
dc.subject | rheology | - |
dc.title | Steric effects and competitive intra- and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: a 1H NMR, rheological and preparative study | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1002/polb.22052 | - |
dc.relation.grant | ARC | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Pham, D. [0000-0001-9383-6699] | - |
Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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