Adelaide Research & Scholarship
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https://hdl.handle.net/2440/61176
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| Type: | Journal article |
| Title: | Syntheses and molecular structures of some polyfluoroaryldiynyl-ruthenium complexes |
| Author: | Bruce, M. Scoleri, N. Skelton, B. White, A. |
| Citation: | Journal of Organometallic Chemistry, 2010; 695(10-11):1561-1568 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2010 |
| ISSN: | 0022-328X 1872-8561 |
| Statement of Responsibility: | Michael I. Bruce, Nancy Scoleri, Brian W. Skelton, Allan H. White |
| Abstract: | Lithiated Ru(C{triple bond, long}CC{triple bond, long}CH)(dppe)Cp* reacts with polyfluoroaromatic compounds C6F5X (X = F, OMe, CN, NO2) and C10F8 to give novel polyfluoroaryldiynyls end-capped with the Ru(dppe)Cp* group. Addition of tcne to Ru(C{triple bond, long}CC{triple bond, long}CC6F5)(dppe)Cp* afforded the butadienynyl Ru{C{triple bond, long}CC[{double bond, long}C(CN)2]C(C6F5){double bond, long}C(CN)2}(dppe)Cp*, while protonation with HBF4·OEt2 resulted in cycloaddition to give [1,3-{Cp*(dppe)RuC{triple bond, long}C}2{μ-C4H(C6F5)2}]BF4. XRD molecular structures of complexes with X = F, CN, OMe and the C10F7 derivative are reported. © 2010 Elsevier B.V. All rights reserved. |
| Keywords: | Alkynyl Diynyl Ruthenium Fluoroaromatic Crystal structure |
| Rights: | Copyright © 2010 Elsevier B.V. All rights reserved. |
| DOI: | 10.1016/j.jorganchem.2010.03.017 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1016/j.jorganchem.2010.03.017 |
| Appears in Collections: | Aurora harvest Chemistry publications |
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