Adelaide Research & Scholarship
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https://hdl.handle.net/2440/70984
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| Type: | Journal article |
| Title: | Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data |
| Author: | Spence, J. George, J. |
| Citation: | Organic Letters, 2011; 13(19):5318-5321 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2011 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Justin T. J. Spence and Jonathan H. George |
| Abstract: | A structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and β-caryophyllene. |
| Keywords: | Sesquiterpenes Magnetic Resonance Spectroscopy Molecular Structure Cyclization Biomimetic Materials Polycyclic Sesquiterpenes |
| Rights: | © 2011 American Chemical Society |
| DOI: | 10.1021/ol202181g |
| Published version: | http://dx.doi.org/10.1021/ol202181g |
| Appears in Collections: | Aurora harvest Chemistry publications |
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