Adelaide Research & Scholarship
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https://hdl.handle.net/2440/71120
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| Type: | Journal article |
| Title: | A Percyanovinylidene−Ruthenium Complex, Ru{═C═C₅(CN)₃[═C(CN)₂]₂}(dppe)Cp* |
| Other Titles: | A Percyanovinylidene -Ruthenium Complex, Ru{=C=C(5)(CN)(3)[=C(CN)(2)](2)}(dppe)Cp* |
| Author: | Bruce, M. Morris, J. Nicholson, B. Skelton, B. White, A. Zaitseva, N. |
| Citation: | Organometallics, 2011; 30(3):653-656 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2011 |
| ISSN: | 0276-7333 1520-6041 |
| Statement of Responsibility: | Michael I. Bruce, Jonathan C. Morris, Brian K. Nicholson, Brian W. Skelton, Allan H. White, and Natasha N. Zaitseva |
| Abstract: | The reaction between Ru(C=CC=CAg)(dppe)Cp* and tcne affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tcne and Ru{C=CC=C[Au(PPh3)]}(dppe)Cp*, together with Ru{C=CC[=C(CN)2]C[Au(PPh3)]=C(CN)2}(dppe)Cp *, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions. © 2011 American Chemical Society. |
| Rights: | Copyright © 2011 American Chemical Society |
| DOI: | 10.1021/om1010885 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1021/om1010885 |
| Appears in Collections: | Aurora harvest 5 Chemistry publications |
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