Adelaide Research & Scholarship
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https://hdl.handle.net/2440/74840
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Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bruce, M. | - |
| dc.contributor.author | Zaitseva, N. | - |
| dc.contributor.author | Skelton, B. | - |
| dc.date.issued | 2012 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 2012; 716:281-284 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.issn | 1872-8561 | - |
| dc.identifier.uri | http://hdl.handle.net/2440/74840 | - |
| dc.description.abstract | Treatment of Ru(CCPh)(PPh3)2Cp 1 with Ag[PF 6] (2/1 molar ratio, in toluene) affords [Ag{η2- PhC2[Ru(PPh3)2Cp]}2]PF6 2, characterised by analysis, spectroscopy and a single-crystal X-ray structure determination. A similar reaction in CH2Cl2 (1/1 molar ratio) gives [{Cp(Ph3P)2Ru}CCHC6H 4CPhC{Ru(PPh3)2Cp}](PF6) 2 4 by oxidative coupling of two alkynyl-Ru radicals. © 2012 Elsevier B.V. All rights reserved. | - |
| dc.description.statementofresponsibility | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton | - |
| dc.language.iso | en | - |
| dc.publisher | Elsevier Science Sa | - |
| dc.rights | © 2012 Elsevier B.V. All rights reserved. | - |
| dc.source.uri | http://dx.doi.org/10.1016/j.jorganchem.2012.05.047 | - |
| dc.subject | Ruthenium | - |
| dc.subject | Alkynyl | - |
| dc.subject | X-ray structure | - |
| dc.subject | Oxidative coupling | - |
| dc.title | Reactions of Ru(C≡CPh)(PPh₃)₂Cp with silver(I): molecular structure of [Ag{η²-PhC₂[Ru(PPh₃)₂Cp]}₂]PF₆ and synthesis of a bis(vinylidene) complex | - |
| dc.title.alternative | Reactions of Ru(C triple bar CPh)(PPh(3))(2)Cp with silver(I): molecular structure of [Ag{eta(2)-PhC(2)[Ru(PPh(3))(2)Cp]}(2)]PF(6) and synthesis of a bis(vinylidene) complex | - |
| dc.type | Journal article | - |
| dc.identifier.doi | 10.1016/j.jorganchem.2012.05.047 | - |
| dc.relation.grant | ARC | - |
| pubs.publication-status | Published | - |
| dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
| Appears in Collections: | Aurora harvest Chemistry publications | |
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