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https://hdl.handle.net/2440/75522
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Type: | Journal article |
Title: | Synthesis of mesoporous Co/Ce-SBA-15 materials and their catalytic performance in the catalytic oxidation of benzene |
Author: | Mu, Z. Li, J. Tian, H. Hao, Z. Qiao, S. |
Citation: | Materials Research Bulletin, 2008; 43(10):2599-2606 |
Publisher: | Pergamon-Elsevier Science Ltd |
Issue Date: | 2008 |
ISSN: | 0025-5408 1873-4227 |
Statement of Responsibility: | Zhen Mu, Jin Jun Li, Hua Tian, Zheng Ping Hao, Shi Zhang Qiao |
Abstract: | Cerium-containing SBA-15 mesoporous materials, with different Ce/Si molar ratios, were synthesized by a direct hydrothermal synthesis method and further modified by impregnation with 10, 15 and 20 wt.% Co. Characterizations by powder X-ray diffraction (XRD), N2 sorption, inductively coupled plasma (ICP) and UV-vis spectroscopy were carried out. The small-angle XRD and N2 sorption characterizations showed that these Co supported materials have less-ordered mesoporous structures with partial blockage of pores, and their specific surface area, pore volume and pore size were relatively lower than those of unsupported cerium-containing SBA-15. Spinel Co3O4 constituted the predominant cobalt phase in the prepared catalysts, and CeO2 was also detected. All the Co supported catalysts exhibited high catalytic activity in the oxidation of benzene. © 2007 Elsevier Ltd. All rights reserved. |
Keywords: | A. Metals A. Oxides B. Chemical synthesis D. Catalytic properties |
Rights: | © 2007 Elsevier Ltd. All rights reserved. |
DOI: | 10.1016/j.materresbull.2007.10.037 |
Published version: | http://dx.doi.org/10.1016/j.materresbull.2007.10.037 |
Appears in Collections: | Aurora harvest 4 Chemical Engineering publications |
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