Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/858
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | A direct comparison of vibrational deactivation of hexafluorobenzene excited by infrared multiple photon absorption and internal conversion |
Author: | Gascooke, J. Alwahabi, Z. King, K. Lawrance, W. |
Citation: | Journal of Chemical Physics, 1998; 109(10):3868-3874 |
Publisher: | American Institute of Physics |
Issue Date: | 1998 |
ISSN: | 0021-9606 1089-7690 |
Abstract: | <jats:p>We report the first direct comparison between energy transfer parameters measured using infrared multiphoton absorption (IRMPA) versus ultraviolet (UV) excitation followed by rapid internal conversion (IC). Highly excited hexafluorobenzene (HFB) molecules in the electronic ground state were prepared by (i) IRMPA by CO2 laser pumping to an average initial energy of 14 500–17 500 cm−1 and (ii) UV excitation to ∼40 300 cm−1 followed by IC. The vibrational deactivation of the highly excited HFB by the monatomic collider gas argon was monitored by time-resolved infrared fluorescence. The results for the two methods are identical within experimental error, demonstrating the viability of IRMPA as a method of state preparation for vibrational deactivation experiments involving large molecules.</jats:p> |
Rights: | © 1998 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. |
DOI: | 10.1063/1.476987 |
Published version: | http://link.aip.org/link/?JCPSA6/109/3868/1 |
Appears in Collections: | Aurora harvest 2 Chemical Engineering publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
hdl_858.pdf | Published version | 174.05 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.