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Type: Journal article
Title: Mechanism of acetal cleavage with methylmagnesium iodide
Author: Abell, A.D.
Massywestropp, R.A.
Citation: Australian Journal of Chemistry: an international journal for chemical science, 1985; 38(7):1031-1036
Publisher: CSIRO Publishing
Issue Date: 1985
ISSN: 0004-9425
Statement of
AD Abell and RA Massy-Westropp
Abstract: The reaction of methylmagnesium iodide with methyl (1R,3S,5R)-1-(furan- 3′-yl)-5-methyl-2,8-dioxabicyclo[3.2.1]octane-3-carboxylate (2) gives products arising from regioselective carbon-oxygen bond fission and intermolecular transfer of the methyl group of the Grignard reagent to the intermediate oxocarbonium ion, in addition to the usual tertiary alcohol.
Rights: © CSIRO 1985
DOI: 10.1071/CH9851031
Appears in Collections:Aurora harvest 2
Chemistry publications

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