Adelaide Research & Scholarship
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https://hdl.handle.net/2440/17903
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| Type: | Journal article |
| Title: | A new approach to the synthesis of carbon chains capped by metal clusters |
| Author: | Bruce, M. Smith, M. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Journal of Organometallic Chemistry, 2003; 670(1-2):170-177 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2003 |
| ISSN: | 0022-328X |
| Statement of Responsibility: | Michael I. Bruce, Mark E. Smith, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
| Abstract: | Reactions of Co3(μ3-CBr)(μ-dppm)(CO)7 with {Au[P(tol)3]}2{μ-(C6-point triple bond; length half of m-dashC)n} (n=2–4) have given {Co3(μ-dppm)(CO)7}{μ3:μ3-C(C6-point triple bond; length half of m-dashC)nC} [n=2 (1), 3 (2), 4 (3)] containing carbon chains capped by the cobalt clusters. Tetracyanoethene reacts with 2 to give {Co3(μ-dppm)(CO)7}2{μ3:μ3-C(C6-point triple bond; length half of m-dashC)2C[=C(CN)2]C[=C(CN)2]C} (4). X-ray structural characterisation of 1, 3 and 4 are reported, that for 3 being the first of a cluster-capped C10 chain. |
| Keywords: | Carbon chains Cobalt clusters Capped clusters C10 chains |
| Description: | Copyright © 2003 Elsevier Science B.V. |
| DOI: | 10.1016/S0022-328X(02)02186-1 |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
| Published version: | http://dx.doi.org/10.1016/s0022-328x(02)02186-1 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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