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https://hdl.handle.net/2440/89473
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Type: | Journal article |
Title: | Sonochemical synthesis and characterization of the new plate-shaped lead(II)-iodo coordination polymer: a precursor to produce a pure phase nano-sized lead(II) oxide |
Author: | Mirtamizdoust, B. Shaabani, B. Khandar, A. Pourradi, H. Abbasityula, Y. Goudarziafshar, H. Viterbo, D. Croce, G. Hojati-Talemi, P. |
Citation: | Journal of Inorganic and Organometallic Polymers and Materials, 2012; 22(6):1293-1299 |
Publisher: | Springer Verlag |
Issue Date: | 2012 |
ISSN: | 1574-1443 1574-1451 |
Statement of Responsibility: | Babak Mirtamizdoust, Behrouz Shaabani, Aliakbar Khandar, Hadi Pourradi, Yunes Abbasityula, Hamid Goudarziafshar, Davide Viterbo, Gianluca Croce, Pejman Hojati-Talemi |
Abstract: | Preparation of plate-shaped nanostructures of a new 1D polymeric lead(II) complex containing the Pb2-(μ-I)2 motif, [Pb(neo)I2] n ,(1) where neo is the abbreviation of neocuproine, using a sonochemical method is described. The new coordination polymer is characterized by scanning electron microscopy, X-ray diffraction (XRD), elemental analysis and infrared spectroscopy. The single crystalline material is obtained using a heat gradient applied to a solution of the reagents. Single-crystal XRD analysis indicates that a coordination number of six for PbII ions, (i.e., PbN2I4) with an asymmetrical coordination sphere and “stereo-chemically active” electron lone pairs. They also show that the chains interact with each other through π–π stacking interactions creating a 3D framework. PbO nanoparticles are obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant. Scanning electron microscopy confirms formation of PbO particles with a size of ~25 nm. |
Keywords: | Lead(II) Nano coordination polymer Plate-shape Nano oxide |
Rights: | © Springer Science+Business Media, LLC 2012 |
DOI: | 10.1007/s10904-012-9754-0 |
Published version: | http://dx.doi.org/10.1007/s10904-012-9754-0 |
Appears in Collections: | Aurora harvest 7 Chemical Engineering publications |
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